Core Audioで可能かと思います。
	Core Audio APIs
	
https://msdn.microsoft.com/en-us/library/windows/desktop/dd370802
以下、取得のみのサンプルです。
#include "ole32.as"
// tofloat todouble by sprocket氏
#module
#defcfunc tofloat double p1
	temp = p1
	return lpeek(temp) >> 29 & 7 | (p1 < 0) << 31 |lpeek(temp, 4) - (p1 ! 0) * 0x38000000 << 3
#defcfunc todouble int p1
	temp = 0.0
	lpoke temp, 4, (p1 & 0x80000000) | (((p1 & 0x7fffffff) >> 3) + ((p1 & 0x7fffffff) ! 0) * 0x38000000)
	lpoke temp, 0, p1 << 29
	return temp
#global
#ifndef IMMDeviceEnumerator
#define global IID_IMMDeviceEnumerator  "{A95664D2-9614-4F35-A746-DE8DB63617E6}"
#define global CLSID_MMDeviceEnumerator "{BCDE0395-E52F-467C-8E3D-C4579291692E}"
#usecom global IMMDeviceEnumerator IID_IMMDeviceEnumerator CLSID_MMDeviceEnumerator
#comfunc global IMMDeviceEnumerator_EnumAudioEndpoints                      3 int,int,var
#comfunc global IMMDeviceEnumerator_GetDefaultAudioEndpoint                 4 int,int,var
#comfunc global IMMDeviceEnumerator_GetDevice                               5 wstr,var
#comfunc global IMMDeviceEnumerator_RegisterEndpointNotificationCallback    6 int
#comfunc global IMMDeviceEnumerator_UnregisterEndpointNotificationCallback  7 int
#endif // IMMDeviceEnumerator
#ifndef IMMDeviceCollection
#define global IID_IMMDeviceCollection "{0BD7A1BE-7A1A-44DB-8397-CC5392387B5E}"
#usecom global IMMDeviceCollection IID_IMMDeviceCollection "{}"
#comfunc global IMMDeviceCollection_GetCount  3 var
#comfunc global IMMDeviceCollection_Item      4 int,var
#endif // IMMDeviceCollection
#ifndef IMMDevice
#define global IID_IMMDevice "{D666063F-1587-4E43-81F1-B948E807363F}"
#usecom global IMMDevice IID_IMMDevice "{}"
#comfunc global IMMDevice_Activate           3 var,int,int,var
#comfunc global IMMDevice_OpenPropertyStore  4 int,var;
#comfunc global IMMDevice_GetId              5 wstr
#comfunc global IMMDevice_GetState           6 var
#endif // IMMDevice
#ifndef IAudioEndpointVolume
#define global IID_IAudioEndpointVolume "{5CDF2C82-841E-4546-9722-0CF74078229A}"
#usecom global IAudioEndpointVolume IID_IAudioEndpointVolume "{}"
#comfunc global IAudioEndpointVolume_RegisterControlChangeNotify    3 int
#comfunc global IAudioEndpointVolume_UnregisterControlChangeNotify  4 int
#comfunc global IAudioEndpointVolume_GetChannelCount                5 var
#comfunc global IAudioEndpointVolume_SetMasterVolumeLevel           6 int,int
#comfunc global IAudioEndpointVolume_SetMasterVolumeLevelScalar     7 int,int
#comfunc global IAudioEndpointVolume_GetMasterVolumeLevel           8 var
#comfunc global IAudioEndpointVolume_GetMasterVolumeLevelScalar     9 var
#comfunc global IAudioEndpointVolume_SetChannelVolumeLevel         10 int,int,int
#comfunc global IAudioEndpointVolume_SetChannelVolumeLevelScalar   11 int,int,int
#comfunc global IAudioEndpointVolume_GetChannelVolumeLevel         12 int,var
#comfunc global IAudioEndpointVolume_GetChannelVolumeLevelScalar   13 int,var
#comfunc global IAudioEndpointVolume_SetMute                       14 int,int
#comfunc global IAudioEndpointVolume_GetMute                       15 var
#comfunc global IAudioEndpointVolume_GetVolumeStepInfo             16 var,var
#comfunc global IAudioEndpointVolume_VolumeStepUp                  17 var
#comfunc global IAudioEndpointVolume_VolumeStepDown                18 var
#comfunc global IAudioEndpointVolume_QueryHardwareSupport          19 var
#comfunc global IAudioEndpointVolume_GetVolumeRange                20 var,var,var
#endif // IAudioEndpointVolume
#ifndef IAudioSessionManager2
#define global IID_IAudioSessionManager2 "{77AA99A0-1BD6-484F-8BC7-2C654C9A9B6F}"
#usecom global IAudioSessionManager2 IID_IAudioSessionManager2 "{}"
#comfunc global IAudioSessionManager2_GetSessionEnumerator           5 var
#comfunc global IAudioSessionManager2_RegisterSessionNotification    6 int
#comfunc global IAudioSessionManager2_UnregisterSessionNotification  7 int
#comfunc global IAudioSessionManager2_RegisterDuckNotification       8 wstr,int
#comfunc global IAudioSessionManager2_UnregisterDuckNotification     9 int
#endif // IAudioSessionManager2
#ifndef IAudioSessionEnumerator
#define global IID_IAudioSessionEnumerator "{E2F5BB11-0570-40CA-ACDD-3AA01277DEE8}"
#usecom global IAudioSessionEnumerator IID_IAudioSessionEnumerator "{}"
#comfunc global IAudioSessionEnumerator_GetCount    3 var
#comfunc global IAudioSessionEnumerator_GetSession  4 int,var
#endif // IAudioSessionEnumerator
#ifndef IAudioSessionControl
#define global IID_IAudioSessionControl "{F4B1A599-7266-4319-A8CA-E70ACB11E8CD}"
#usecom global IAudioSessionControl IID_IAudioSessionControl "{}"
#comfunc global IAudioSessionControl_GetState                            3 var
#comfunc global IAudioSessionControl_GetDisplayName                      4 var
#comfunc global IAudioSessionControl_SetDisplayName                      5 wstr,int
#comfunc global IAudioSessionControl_GetIconPath                         6 var
#comfunc global IAudioSessionControl_SetIconPath                         7 wstr,int
#comfunc global IAudioSessionControl_GetGroupingParam                    8 var
#comfunc global IAudioSessionControl_SetGroupingParam                    9 var,int
#comfunc global IAudioSessionControl_RegisterAudioSessionNotification   10 int
#comfunc global IAudioSessionControl_UnregisterAudioSessionNotification 11 int
#endif // IAudioSessionControl
#ifndef IAudioSessionControl2
#define global IID_IAudioSessionControl2 "{bfb7ff88-7239-4fc9-8fa2-07c950be9c6d}"
#usecom global IAudioSessionControl2 IID_IAudioSessionControl2 "{}"
#comfunc global IAudioSessionControl2_Release                             2
#comfunc global IAudioSessionControl2_GetState                            3 var
#comfunc global IAudioSessionControl2_GetDisplayName                      4 var
#comfunc global IAudioSessionControl2_SetDisplayName                      5 wstr,int
#comfunc global IAudioSessionControl2_GetIconPath                         6 var
#comfunc global IAudioSessionControl2_SetIconPath                         7 wstr,int
#comfunc global IAudioSessionControl2_GetGroupingParam                    8 var
#comfunc global IAudioSessionControl2_SetGroupingParam                    9 var,int
#comfunc global IAudioSessionControl2_RegisterAudioSessionNotification   10 int
#comfunc global IAudioSessionControl2_UnregisterAudioSessionNotification 11 int
#comfunc global IAudioSessionControl2_GetSessionIdentifier               12 var
#comfunc global IAudioSessionControl2_GetSessionInstanceIdentifier       13 var
#comfunc global IAudioSessionControl2_GetProcessId                       14 var
#comfunc global IAudioSessionControl2_IsSystemSoundsSession              15
#comfunc global IAudioSessionControl2_SetDuckingPreference               16 int
#endif // IAudioSessionControl2
#ifndef ISimpleAudioVolume
#define global IID_ISimpleAudioVolume "{87CE5498-68D6-44E5-9215-6DA47EF883D8}"
#usecom global ISimpleAudioVolume IID_ISimpleAudioVolume "{}"
#comfunc global ISimpleAudioVolume_SetMasterVolume  3 int,int
#comfunc global ISimpleAudioVolume_GetMasterVolume  4 var
#comfunc global ISimpleAudioVolume_SetMute          5 int,int
#comfunc global ISimpleAudioVolume_GetMute          6 var
#endif // ISimpleAudioVolume
	sdim bufMB, 1024
	newcom devEnum, IMMDeviceEnumerator
	IMMDeviceEnumerator_GetDefaultAudioEndpoint devEnum, 0, 0, p
	if ( stat ){ end }
	newcom dev, IMMDevice, -1, p
	iid = 0x5cdf2c82, 0x4546841e, 0xf70c2297, 0x9a227840
	IMMDevice_Activate dev, iid, 1, 0, p
	if ( stat ){ end }
	newcom aev, IAudioEndpointVolume, -1, p
	IAudioEndpointVolume_GetMute aev, p1
	IAudioEndpointVolume_GetMasterVolumeLevelScalar aev, p2
	p3 = int(todouble(p2) * 100)
	bufMB += strf("IAudioEndpointVolume Mute: %d Vol: %d\n\n", p1, p3)
	iid = 0x77aa99a0, 0x484f1bd6, 0x652cc78b, 0x6f9b9a4c
	IMMDevice_Activate dev, iid, 1, 0, p
	if ( stat ){ end }
	newcom sm, IAudioSessionManager2, -1, p
	IAudioSessionManager2_GetSessionEnumerator sm, p
	if ( stat ){ end }
	newcom sEnum, IAudioSessionEnumerator, -1, p
	IAudioSessionEnumerator_GetCount sEnum, p
	bufMB += strf("IAudioSessionEnumerator_GetCount: %d\n\n", p)
	bufMB += strf("ProcessID State Mute  Vol Name\n")
	repeat p
		IAudioSessionEnumerator_GetSession sEnum, cnt, p
		newcom sc, IAudioSessionControl2, -1, p
		IAudioSessionControl2_GetProcessId sc, p1
		IAudioSessionControl2_GetState sc, p2
		IAudioSessionControl2_GetDisplayName sc, p
		dupptr dp, p, 1024, 2
		querycom sav, sc, ISimpleAudioVolume
		ISimpleAudioVolume_GetMute sav, p3
		ISimpleAudioVolume_GetMasterVolume sav, p4
		p5 = int(todouble(p4) * 100)
		bufMB += strf("%9d  %4d %4d %4d %s\n", p1, p2, p3, p5, cnvwtos(dp))
		CoTaskMemFree p
		delcom sc
	loop
	title "Test Core Audio"
	objmode 2
	mesbox bufMB, ginfo_winx, ginfo_winy, 4
	delcom sEnum
	delcom sm
	delcom aev
	delcom dev
	delcom devEnum
	stop